ElementalsAll elements
Halogen · Element 9

Fluorine

Fluorine is a highly reactive halogen gas; its fluoride compounds have very different properties from the pure element.

Fluorine illustrates why an element and its compounds can behave very differently.

Explore Fluorine's atom
Atomic number
9
Standard atomic weight
18.998403162(5)
Family
Halogen
Period
2
Group
17
Standard state
Gas

In everyday life

Fluoride compounds are used in many toothpastes to protect teeth.

Something to remember

Fluorine has the highest electronegativity on the Pauling scale.

Meet its electrons

[He] 2s2 2p5

Published neutral-atom ground-state configuration; excited atoms and ions can differ.

Electrons per shell: 2 · 7.

The playground shows an illustrative shell model. Real electrons are described by quantum orbitals, rather than tiny planets traveling along fixed paths.

A connection to explore

Fluorine and chlorine are halogens, with related but distinct chemistry.

Meet Chlorine (Cl)

Properties and conditions

Standard atomic weight
18.998403162(5)CIAAW 2024 standard atomic weight (dimensionless). Parentheses give uncertainty in the last quoted digits. Source flags: none.CIAAW standard atomic weights ↗ · Retrieved 2026-10-15
Standard state
GasPubChem classification, including explicit predictions where stated. Reference temperature and pressure are not supplied in the table.PubChem periodic table ↗ · Retrieved 2026-10-15
First ionisation energy
17.423 eVEnergy to remove the first electron from an isolated neutral gas-phase atom. Uncertainty is not supplied.PubChem periodic table ↗ · Retrieved 2026-10-15
Electronegativity
3.98 Pauling scaleA dimensionless relative measure; values depend on the chosen scale. Uncertainty is not supplied.PubChem periodic table ↗ · Retrieved 2026-10-15
Melting point
53.53 KPubChem reported value. Pressure, allotrope and measurement uncertainty are not specified in the table; consult the cited source.PubChem periodic table ↗ · Retrieved 2026-10-15
Boiling point
85.03 KPubChem reported value. Pressure and measurement uncertainty are not specified in the table; consult the cited source.PubChem periodic table ↗ · Retrieved 2026-10-15
Density
0.001696 g/cm³PubChem reported value. Temperature, pressure, allotrope and measurement uncertainty are not specified in the table; gas densities are especially condition-dependent.PubChem periodic table ↗ · Retrieved 2026-10-15
Oxidation states
-1Selected PubChem oxidation states; formal electron bookkeeping, not a list of stable free-ion charges or every possible compound.PubChem periodic table ↗ · Retrieved 2026-10-15
Discovery
1670PubChem discovery attribution. Ancient knowledge and competing priority claims cannot always be represented by a single year.PubChem periodic table ↗ · Retrieved 2026-10-15
Atomic radius
135 pmPubChem tabulated radius. Radius definitions depend on bonding and convention; measurement definition and uncertainty are not supplied in this table.PubChem periodic table ↗ · Retrieved 2026-10-15
Electron affinity
3.339 eVPubChem reported gas-phase electron affinity. Sign conventions and electronic states matter; uncertainty is not supplied in this table.PubChem periodic table ↗ · Retrieved 2026-10-15

Isotopes, abundance and decay

Isotopes share a proton count but have different neutron counts. This selection includes naturally tabulated compositions and a reference isotope for other elements. It is not a list of every known isotope.

Explore 1 isotope of F
Evaluated ground-state isotopes of F
IsotopeRelative atomic massNatural fractionHalf-lifeDecay
F-1918.99840316273(92)1No decay observedNo decay tabulated

Fractions use NIST’s terrestrial isotopic compositions, which can vary by sample. Parentheses denote uncertainty in the last digits. Half-lives and decay branches use NUBASE2020; # marks estimates, >/< mark limits. “No decay observed” follows that evaluation and does not prove permanent stability. Decay branch intensities are percentages; SF means spontaneous fission, EC electron capture, IT an isomeric transition.

NUBASE2020 ↗ · NIST compositions ↗

Follow the science

Use these original references to explore the data and context. Atomic weights can vary with isotope composition; values for elements without stable isotopes may describe a representative isotope rather than a standard atomic weight.